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Bruker Corporation 20 saint; version 5.0 ed
20 Saint; Version 5.0 Ed, supplied by Bruker Corporation, used in various techniques. Bioz Stars score: 90/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
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Article Title: Axial Redox Tuning at a Tetragonal Cobalt Center.
Article Snippet: Square pyramidal cobalt complexes were prepared to study their multielectron redox properties.. To build a stable redox-active cobalt complex, the combination of a tridentate PNP (acriPNP− = 4,5-bis(diisopropylphosphino)-2,7,9,9-tetramethyl-9H-acridin-10-ide) ligand with a bidentate ligand, such as 2,2′-bipyridine, 2-(o-phenyl)pyridine, biphenylene, and their analogues, was employed.. In a cobalt complex having a tetragonal structure, the dx−y orbital possesses an antibonding character and must remain empty for its structural integrity, while the dz orbital acts as a redox-active frontier molecular orbital (FMO).

Article Title: <i>N</i> ‐Alkoxy Carboxamide Stabilized Tin(II) and Germanium(II) Complexes for Thin‐Film Applications
Article Snippet: A new series of germanium (1-5) and tin (6-10) complexes were successfully synthesized by employing N-alkoxy functionalized carboxylamide as the stabilizing ligands and these complexes could potentially serve as precursors for thin film applications.. All complexes were characterized by Fourier transform (FT) infrared, and nuclear magnetic resonance spectroscopies as well as elemental and thermogravimetric (TG) analyses.. The single crystal X-ray study of complexes 5 and 10 revealed that they crystalized in the monoclinic space group (P2(1)/c) as monomers.

Article Title: Argentobaumhauerite: name, chemistry, crystal structure, comparison with baumhauerite, and position in the Lengenbach mineralization sequence
Article Snippet: The crystal structure of argentobaumhauerite is reported for the first time from a sulfosalt aggregate from Lengenbach deposit, Binntal, Switzerland.. The chemical formula of argentobaumhauerite, calculated in agreement with the results of structure determination is Cu0.06Ag1.20Tl0.18Pb21.46Sb0.56As32.28S72.26.. The difference from the idealized baumahuerite formula, Pb12As16S36, and from the formula of Ag-, Tland Sbfree baumhauerite from Moosegg, Austria, Pb11.80As16.28S35.92, expresses the Ag + As and Tl + As substitution for 2Pb.

Article Title: Palladium(II) Complexes of the Hemilabile Pincer Ligand PPh(o-C6H4SMe)2as Highly Active and Recyclable ­Mizoroki-Heck Catalysts
Article Snippet: PdII complexes with PPh(o-C6H4SMe)2 acting as a pincer ligand in an S,S′,Por S,P-coordination mode have been synthesized.. The complexes include [PdCl2{PPh(o-C6H4SMe)2}] (1), [Pd(Me)Cl{PPh(o-C6H4SMe)2}] (2), and [Pd(X){PPh(oC6H4SMe)2}]A [A = CF3SO3, X = Cl (3); A = CF3SO3, Me (4); A = PF6, X = Me (5)].. Insertion of CO into the Pd–Me bond of these complexes leads to [Pd(COMe)Cl{PPh(o-C6H4SMe)2}] (6) and

Article Title: Pd-Oxazolone complexes conjugated to an engineered enzyme: improving fluorescence and catalytic properties.
Article Snippet: 42 SAINT, Version 5.0 ed, Bruker Analytical X-Ray Systems, Madison, WI, 1998.

Article Title: Synthesis of esters of diaminotruxillic bis-amino acids by Pd-mediated photocycloaddition of analogs of the Kaede protein chromophore
Article Snippet: SAINT, Version 5.0 ed; Bruker Analytical X-Ray Systems: Madison, WI, USA, 1998.

Article Title: The crystal structure of veenite
Article Snippet: The crystal structure of veenite is reported for the first time from a sample from the type locality of Madoc (Ontario, Canada).. It has been solved and refined by X-ray single-crystal diffraction on the basis of 4973 observed reflections (with Fo > 4σ(Fo)) with a final R1 = 0.0396.. Veenite is monoclinic P21, with unit-cell parameters a = 8.429(2), b = 26.069(5), c = 8.962(2) Å, β = 117.447(2).

Article Title: Heteroleptic strontium complexes stabilized by donor-functionalized alkoxide and β-diketonate ligands.
Article Snippet: Heteroleptic complexes of strontium (1–7) were prepared by employing β-diketonates and donorfunctionalized alkoxides as coordinating ligands.. The results illustrate the effect of alkoxide substituent groups on the overall structures of the complexes.. The presence of a terminal methoxy group in the alkoxide ligands leads to the formation of trimeric complexes 1–4, whereas the substituents on the amine nitrogen prove to have less influence in determining the structure.



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